O
Orclever
Back to Journal
Research Article Open AccessOrclever Native

Biobased Alkyd Acrylic Hybrid Core Shell Approach

Beyhan Erdoğan1✉,
Ozgur Sen2
1DYO Paint Factory
2DYO Paint Factory
Published:December 31, 2023
DOI: 10.56038/ejrnd.v3i4.328
Vol. 3, No. 4

Abstract

The main objective of this work was to synthesize bio based alkyd-arcylic hybrid emulsion by using core shell approach.  Step by step growing polymerization was used for the preparation of the bio-based alkyd resin. Bio-based sebacic acid was used in the synthesis. In the core shell approach; shell part contains acrylic polymer, core part contains bio based alkyd emulsion, which was synthesized by phase inversion. The acrylic shell was synthesized in the presence of the alkyd resin by the emulsion polymerization method. 

Keywords
Bio based alkydacrylicemulsioncore shellpolymerization

References

  1. 1.Ifijen, H. I., Maliki, M., Ifeanyi, J. O., Aghedo, O.N., Ohioocheoya, EçB., Review on Solvents Based Alkyd Resins and Water Borne Alkyd Resins: Impacts of Modification on Their Coating Properties, Chemistry Africa , 2022, 5, 211–225.
  2. 2.Yousefi, A. A., Pishvaei, M., Yousefi, A., Preparation of Water-Based Alkyd/Acrylic Hybrid Resins, The Progress in Color, Colorants and Coatings (PCCC), 2011, 4, 15-25.
  3. 3.Elrebii, M., Mabrouk, A.B., Boufi, S., Synthesis and properties of hybrid alkyd–acrylic dispersions and their use in VOC-free waterborne coatings, Progress in Organic Coatings, 2014, 77, 757-764.
  4. 4.Elrebii, M., Kamounb, A., Boufi, S., Waterborne hybrid alkyd–acrylic dispersion: Optimization of the composition using mixture experimental designs, Progress in Organic Coatings, 2015, 87, 222–231.
  5. 5.Guyot, A., Landfester, K., Schorkc, F.J., Wang, C., Hybrid polymer latexes, Progress in Polymer Science, 2007, 32, 1439-1461.
  6. 6.Heiskanen, N., Jämsä, S, Paajanen, L., Koskimies, S., Synthesis and performance of alkyd–acrylic hybrid binders, Progress in Organic Coatings, 2010, 67, 329-338.
  7. 7.Nabuurs, T., Bajjards, R.A., German, A.L, Alkyd-acrylic hybrid systems for use as binders in waterborne paints, Progress in Organic Coatings,1996 , 27,163-17
  8. 8.Weissenborn, P.K., Motiejauskaite, A., Emulsification, drying and film formation of alkyd emulsions, Progress in Organic Coatings, 2000, 40, 253-266.
  9. 9.Watson, D.J., Mackley, M.R., The rheology of aqueous emulsions prepared by direct emulsification and phase inversion from a high viscosity alkyd resin, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2002, 196, 121–134.
  10. 10.Östberg, G., Hulden, M., Bergenstahl, B., Holmberg, K., Alkyd emulsions, Progress in Organic Coatings, 1994, 24, 281-297.
  11. 11.Östberg, G., Bergenstahl, B., Hulden, M., Influence of emulsifier on the formation of alkyd emulsions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1995, 94, 161-171.
  12. 12.Kivit, P.J.J., Aramendia, E., Cabrera, A.A., Rios, L. Water-Based Coatings Based on Mixtures of Acrylic Dispersions and Alkyd Emulsions, 2009, Macromolecular Symposia, 283–284, 290–299.
  13. 13.Karlsson, O.J., Deriss, M.J., Morphologies and droplet sizes of alkyd–acrylic hybrids with high solids content, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 245, 115–125
Download PDF
Cite This Article
Erdoğan, B., Sen, O. (2023). Biobased Alkyd Acrylic Hybrid Core Shell Approach. *The European Journal of Research and Development*, 3(4), 218-228. https://doi.org/10.56038/ejrnd.v3i4.328

Bibliographic Info

JournalThe European Journal of Research and Development
Volume3
Issue4
Pages218–228
PublishedDecember 31, 2023
eISSN2822-2296